First of all you need to explore all the skill available in the default wc3.
From there, you can make you own skill that might related or solve your problem.
How to increase unit armour
There are several skill can increase unit armour such as inner fire, scroll of protection (not sure the name but it can heal unit and increase armour temporary).
Dota circle of power is actually make the unit invulnerable and omni knight ultimate make the armour to 9999 (not invulnerable).
There is an action inside the trigger "unit-make unit invulnerable" or simply use the human paladin hero skill.
From there, you can make you own skill that might related or solve your problem.
How to increase unit armour
There are several skill can increase unit armour such as inner fire, scroll of protection (not sure the name but it can heal unit and increase armour temporary).
Dota circle of power is actually make the unit invulnerable and omni knight ultimate make the armour to 9999 (not invulnerable).
There is an action inside the trigger "unit-make unit invulnerable" or simply use the human paladin hero skill.